Spectrophotometric Determination of Vanadium with Oxine
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چکیده
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EXTRACTIVE SPECTROPHOTOMETRIC DETERMINATION OF VANADIUM WITH ANTHRANILIC ACID IN PRESENCE OF PYRIDINE
Vanadium (III) gives a greenish- yellow complex with anthranilic acid in presence of pyridine. The complex is extractable with chloroform and is used for photometric determination of vanadium by measuring the absorbance at 390 nm against a reagent blank. Beer's Law holds good in the range of 1-20 pg V/ml. Moderate amounts of Pb (II) , Ca (II) , Sr (II) , Ba (II) , Cd (II) , Mg (II) , Mn (II...
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A simple and sensitive kinetic-spectrophotometric method is described for the determination of vanadium and the possible mechanism of catalytic reaction is proposed. The method is based on the vanadium(V)-catalyzed oxidation of 1,8-diaminonaphthalene (DNA) by potassium bromate (Tiron as activator) at pH 3.8 and 40 degrees C. The reaction was monitored spectrophotometrically by measuring the inc...
متن کاملDirect and Second Order Derivative Spectrophotometric Determination of Vanadium (IV)
A new spectrophotometric method has been developed for the determination of vanadium (IV) in aqueous dimethyl formamide using 2-hydroxy-3-methoxy benzaldehyde thiosemicarbazone (HMBATC) as a chromophoric reagent. The vanadium (IV) reacts with HMBATC forming a dark yellowish green colored water soluble complex, [V(IV)–HMBATSC] in the pH range of 4.0–7.0. The yellowish green colored complex shows...
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A simple and sensitive extractive- spectrophotometric method for thedeterrnination of trace amounts of vanadium(V) is reported. The method is based on the quantitative extraction of the anion complex of V(V) with 4-(2-pyridy1azo)-resorcinol with tetrabutylammonium perchlorate into chloroform, followed by spectrophotometric measurements at 554 nm. Beer's law is obeyed over the concentration ...
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Formation equilibria of dioxy vanadium (V) complex with alanine in acidic media (pH<2.3) has been investigated potentiometrically and spectrophotometrically. In this condition the 1:1 complex has the formula VO2Y, where Y¯ represent the fully dissociated aminocarboxylate anion. The stability constant of VO2Y was determined as log KVO2Y=11.32±<e...
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1957
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.78.533